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样品: | allylic amines | 项目: | 合成allylic amines |
The hydrozirconation of alkynes with zirconocene hydro-chloride and the dimethylzinc-mediated addition of
alkenylzirconocenes to diphenylphosphinoyl imines can be greatly accelerated with microwave irradiation, resulting in a convenient and rapid one-pot process for the preparation of synthetically useful allylic mines.
Peter Wipf, Jelena Janjic and Corey R. J. Stephenson
Department of Chemistry, University of Pittsburgh, Pittsburgh Pennsylvania, 15260, USA.
E-mail:pwipf@pitt.edu; Fax: 1-412-624-0787; Tel: 1-412-624-8606
Department of Pharmaceutical Sciences, University of Pittsburgh, Pittsburgh, PA 15261,
USA
Center for Chemical Methodologies & Library Development, University of Pittsburgh,
Pittsburgh, PA 15260, USA
Received 23rd December 2003, Accepted 19th January 2004
First published as an Advance Article on the web 28th January 2004